Hydrothermal synthesis, crystal structure and third-order non-linear optical property of a discrete decanuclear iodocuprate(I) [CuI10H2I16]4− with [NiII(phen)3]2+ as a template

New copper(I) iodides with bisimidazole molecules: Synthesis, structural characterization and photoluminescence property

“…This kind of I -coordination mode appears generally in the metal halides with a ribbon structure. 16 I2 adopts a special 4 bridging mode, namely an umbrella-like coordination mode, which has ever been observed in the reported compounds [Ni(phen)]3[Cu8I15H] (phen = 1,10-phenanthronline), 17 [Cu14I14(dabco)5(py)], 10 and [ahp][Cu3Br4] (ahp + = 2-amino-3-hydroxypyridinium). 18 The fourth Cu + center lies below the three Cu + plane, and this Cu-I distance (2.8236(11) Å) is obviously longer than those of the -8 -other three (2.6420(13)-2.6877(10) Å).…”

Tetrakis[2‐(2‐pyridyl)pyridinium] Tetra‐μ3‐iodo‐hexa‐μ2 ‐iodo‐dodecaiodohexabismuthate and Bis[tris(2,2′‐bipyridine)ruthenium(II)] Di‐μ4‐iodo‐octa‐μ2 ‐iodo‐dodecaiodohexabismuthate.

“…The main group halometallate materials display extensive structural diversity, as the anionic inorganic component ranges from discrete clusters (zero-dimensional) to polymeric structures (one-, two-or three-dimensional) depending on the main group metal and on the speci®c synthetic conditions employed. To date, main group halometallate materials based on Cu I (Yu et al, 2003), Sn II (Xu & Mitzi, 2003), Sb III (Mousdis et al, 1998), Te IV (Ryan & Xu, 2004), Pb II (Zhu et al, 2003) and Bi III (Mousdis et al, 1998;Eickmeier et al, 1999;Lindsjo et al, 2005) have been synthesized and structurally characterized.…”

In situ Alkylation of 4,4′‐Vinylenedipyridine for Inorganic‐Organic Iodides/Iodidomercurates

“…Organic‐inorganic hybrids transition metal‐halides have attracted more and more attention because of their various structures and physical properties from both components, which may show potential applications in photoelectricity, magnetism, and catalysis . For example, compound [Ni II (phen) 3 ] 2 [Cu 10 H 2 I 16 ] with discrete decanuclear iodocuprate(I) [Cu I 10 H 2 I 16 ] 4– shows excellent third‐order non‐linear optical property, (C n H 2 n +1 NH 3 ) 2 MnCl 4 ( n = 1, 2, 3) exhibits room temperature photoluminescence peaks at 597, 588, and 602 nm, respectively . Compound [(C 6 H 5 (CH 2 ) 2 NH 3 ) 2 ]CrCl 4 shows paramagnetic‐ferromagnetic transition at the critical temperature around 40–50 K .…”