Hydrothermal synthesis and thermodynamic properties of 2CaO·3B2O3·H2O

Preparation, characterization and luminescence properties of a new hydrous red phosphor CaB3O5(OH):Eu3+ with different morphologies

“…The low‐magnification and high‐magnification SEM images of CaB 3 O 5 (OH):Eu 3 + synthesized with and without surfactants are shown in Figure . Figure (a) show that the sample CBH–0.05Eu–NON exhibits a sphere‐like microstructure, which is constructed of many regular microrods with a diameter of about 200 nm and length of 30 μm, similar to that of 2CaO·3B 2 O 3 ·H 2 O . Figure (b) show that the sample CBH–0.05Eu–PEG4000 has good dispersity; it exhibits irregular microsheets with a thickness of about 200 nm and length of 25 μm.…”

“…It was first synthesized by Clark and colleagues, who determined its structure. So far, there have been few studies on this compound, therefore 2CaO·3B 2 O 3 ·H 2 O with different morphologies was prepared using several methods and its thermochemical and optical properties were also investigated . The preparation was found to exhibit excellent non‐linear optical (NLO) properties.…”

“…So far, there have been few studies on this compound, therefore 2CaO·3B 2 O 3 ·H 2 O with different morphologies was prepared using several methods [13,14] and its thermochemical and optical properties were also investigated. [15,16] The preparation was found to exhibit excellent non-linear optical (NLO) properties. However, to date there have been no reports on the preparation and luminescence properties of CaB 3 O 5 (OH) host phosphors.…”

Hydrothermal synthesis and thermochemistry of metalloborophosphate of Na2[CuB3P2O11(OH)]·0.67H2O

“…As for the thermochemistry of borates, we have measured the standard molar enthalpies of formation of many metal borates [4][5][6][7][8][9][10][11]. However, studies of the thermochemistry of the borophosphates are not reported in the literature.…”

Hydrothermal synthesis and thermodynamic properties of 2ZnO·3B2O3·3H2O

“…As for the thermochemistry of borates, we have measured the standard molar enthalpies of formation of some alkaline and alkaline-earth metal borates [4][5][6][7][8][9][10]. This paper reports the determination of this important zinc borate and an estimate of the D f G m and S m of this borate by a group contribution method.…”