Hydrothermal synthesis and characterization of a new vanadyl sulfate compound: crystal structure of [V(IV)OSO4(H2O)4]·SO4·[H2N(C2H4)2NH2]

The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds

“…596 In many sulfatebound V(IV) structures, pyridyl-type ligands are effective stabilizing ligands, [597][598][599][600][601] although other ligands can be used. A monomeric vanadyl complex with bidentate sulfate, [VO(terpy)SO 4 ] was structurally characterized (115).…”

Synthesis, Crystal Structure, and Magnetic Properties of a Three‐Dimensional Hydroxide Sulfate: Mn5(OH)8SO4

“…[22,23] M. I. Khan et al reported a layered vanadium sulfate. [24] In most of the previous compounds prepared by hydrothermal techniques, the layers were like modified brucite, having some of the [MO 6 ] (M = octahedrally coordinated metal element) octahedra replaced by [TO 4 ] tetrahedra above and below the vacancies, whereas now a truly brucite-type magnetic layered compound has been reported by S. Vilminot et al [25] There are much fewer 3D compounds reported. Wright et al reported a 3D scandium sulfate.…”

[NC4H12]2[(UO2)6(H2O)2(SO4)7]: the first organically templated actinide sulfate with a three-dimensional framework structure

“…Doedens et al have synthesised a layered vanadyl sulfate. 8 Rao et al recently reported two 1-D cadmium sulfates, which were synthesised using the 'amine-sulfate' method. 9 Rao et al have also reported a layered iron sulfate.…”