Abstract:Polycarbosilanes exhibit desirable physiochemical properties such as high thermal stability, elastomeric behavior, diverse functional group tolerance, electronic delocalization, and ease of synthesis. New ceramic precursors, fire‐retardant materials, and flexible conducting polymers have been created using polycarbosilanes. Catalytic hydrosilylation provides a convenient synthetic route to these materials. With its tolerance of many functional groups, catalytic hydrosilylation offers one‐step syntheses of both… Show more
“…Though the hydrosilylation of internal alkynes is comparatively less explored than that of terminal alkynes, it is of considerable importance to organic synthesis as it produces silylated alkenes in a stereoselective fashion [282] (Scheme 34). …”
Section: Hydrosilylation Of Internal Alkynesmentioning
“…Though the hydrosilylation of internal alkynes is comparatively less explored than that of terminal alkynes, it is of considerable importance to organic synthesis as it produces silylated alkenes in a stereoselective fashion [282] (Scheme 34). …”
Section: Hydrosilylation Of Internal Alkynesmentioning
“…1 H and 29 Si NMR spectra were measured by a Bruker ARX-300 or a Jeol JNM-LA600 instrument using benzene-d 6 solvent. IR spectra were recorded on a Perkin Elmer Spectrum One spectrometer.…”
“…[2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18] The rapid progresses in this area, especially the recent booming in the click chemistry, are quickly changing the map and widening the territory. We therefore think it is high time to organize this Special Article Series called ''New Frontiers in Functional Polymers''.…”
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