Abstract:Metal organic frameworks (MOFs) have shown promising adsorptive desulfurization (ADS) capacity yet remains great challenges to maintain excellent performance in presence of water. Guided by the density function theoretical (DFT) calculations, we select bromine modified linkers with different substitution degrees to construct MIL‐47‐xBr to regulate the porosity and hydrophobicity. The optimized MIL‐47‐Br exhibits the highest saturation dibenzothiophene (DBT) capacity of 179.2 mgS g−1 from the hydrous oil, surpa… Show more
“…The challenges of the above methods arise from the instability of these external stimuli, the manufacturing cost of the corresponding device, and the limited range of surface contact angle control. Similarly, chemical modification [20][21][22] and plasma spraying techniques 23 are employed to augment the hydrophilicity of surfaces to achieve desired surface properties. The above methods often encounter difficulties in achieving the specific contact angle requirements for a stable interface.…”
Developing a stable, reliable, and industrially compatible method to control hydrophobicity is crucial for separation, transportation, and the generation of special surfaces. The e-HMS-PDMS silica gel nanoparticle coating was prepared...
“…The challenges of the above methods arise from the instability of these external stimuli, the manufacturing cost of the corresponding device, and the limited range of surface contact angle control. Similarly, chemical modification [20][21][22] and plasma spraying techniques 23 are employed to augment the hydrophilicity of surfaces to achieve desired surface properties. The above methods often encounter difficulties in achieving the specific contact angle requirements for a stable interface.…”
Developing a stable, reliable, and industrially compatible method to control hydrophobicity is crucial for separation, transportation, and the generation of special surfaces. The e-HMS-PDMS silica gel nanoparticle coating was prepared...
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