Hydrophilic Ti-MWW for catalyzing epoxidation of allyl alcohol

Abstract

Titanosilicates are widely applied in the alkene epoxidation reactions with high reaction rate and selectivity to desired products. Their catalytic performance depends on the structure topology, the micro-environment of Ti active sites, and the hydrophobicity/hydrophilicity of zeolite framework. Herein, we focus on a hydrophilic substrate of allyl alcohol (AAL) and investigated catalytic performance of four titanosilicates (TS-1, Ti-MOR, Ti-MWW, and Re-Ti-MWW) in the AAL epoxidation reaction with hydrogen peroxide as the oxidant. Among them, Re-Ti-MWW, synthesized via the post-modification of Ti-MWW with piperidine, exhibited the highest activity. Moreover, the preferred solvent changed from MeCN for Ti-MWW to H2O for Re-Ti-MWW. The relative diffusion rate of AAL over Re-Ti-MWW was up to 466 × 10-7 s-1, much larger than those of other zeolites. The higher diffusion rate of Re-Ti-MWW was probably derived from the higher framework hydrophilicity as revealed by the smaller water contact angle of Re-Ti-MWW compared to the other zeolites, which contributed to the high activity in AAL epoxidation. In the continuous slurry reactor, Re-Ti-MWW achieved a high catalytic lifetime of 163 h, with the selectivity of desirable glycidol product maintained at > 97% in the H2O solvent system, showing high potential as an industrial catalyst for the AAL epoxidation reaction.

Precision design of Ti sites for unprecedented catalytic performance

“…incorporated titanium (Ti) into porous silica frameworks to endow Ti sites with catalytic oxidation ability [ 1 ]. Nowadays, catalytic oxidation reactions using titanium silicate materials have become one of the most important processes in the petrochemical industry [ 2 , 3 ]. Among them, catalytic oxidative desulfurization (ODS) has emerged as a promising technique for removing thiophenic sulfurs from fuels to meet stringent environmental regulations [ 4 ].…”