Sulfate concentration and pH were determined in surface water, groundwater, and precipitation samples collected in the Filson Creek watershed to evaluate the sources of sulfate in Filson Creek. During and immediately after snowmelt, sulfate concentrations in Filson Creek increased from about 2 to 14 mg/l. Concurrently, H + ion activity increased from an average of 10 -6-6 to 10 -5'5. These changes suggest that sulfate acidity is concentrated in the snowpack at snowmelt, which is similar to changes reported in Scandinavia in areas subject to acid precipitation. Mass balance calculations indicate that the surfate contribu. tion from groundwater during snowmelt was minimal in comparison to that from snow. During base flow, sulfate did not appreciably increase from the headwaters of Filson Creek to the mouth, even though sulfate was as high as 58 mg/l in groundwater discharging to the creek from surficial materials overlying a sulfide-bearing mineralized zone in the lower third of the watershed. Approximately 10.6 kg of surfate per hectare per year was retained in 1977. ' INTRODUCTION Acid precipitation caused by the oxidation and hydrolysis of SO,, and NO,, emissions from the combustion of fossil fuels has lowered the pH of poorly buffered surface waters in Canada [Beamish, 1976], Scandinavia [Braekke, 1976], and the Adirondack Mountains of New York [Schofield, 1976]. Acidification of poorly buffered surface waters results in reduced diversity and abundance of fish, zooplankton, benthos, phytoplankton, and aquatic macrophytes [Gorham, 1976]. Acid precipitation especially impacts surface water quality at snowmelt. Gjessing et al. [1976], Haapala et al. [1975], and Henrikson and Wright [1977] found that fractionation and concentration of pollutants in the snowpack during the early phases of snowmelt caused large decreases in the pH of surface waters in Scandinavia. Johannessen and Henrikson [1978], and Johannessen et al. [1975] found from field and experimental studies in Norway that the concentrations of major cations and anions, H + ions, and heavy metals were from 3 to 5 times higher in the first fractions of meltwater than in the bulk snowpack.