The GEOTREF project aims at developing high enthalpy geothermal energy in fractured reservoirs. It focuses on active volcanic islands and especially on the Basse-Terre Island (Guadeloupe archipelago). As part of this project we measured several petrophysical properties to better understand how fluids flow in the hydrothermal system, provide a set of parameters to modelers and build dataset for the future interpretation of * Corresponding author at: UMR 7359 GeoRessources, Ecole Nationale Supérieure de Géologie. 2 Rue du Doyen Marcel Roubault-BP 10162. 54505 Vandoeuvre-lès-Nancy cedex .K-1). Specific heat capacity is close for all lithothypes (0.75-0.97 kJ.kg-1 .K-1). Advancing hydrothermal alteration removes magnetic minerals and transforms initial rocks by replacing initial plagioclases and pyroxenes in neoformed chlorite, white micas, quartz, epidote and clay minerals modifying the shape of pore network. Hydrothermal alteration results in a reduction of pore throat diameters. It tends to decrease petrophysical differences between lavas and debris flows increasing porosity and permeability of effusive rocks while the opposite effects are observed in debris flows.