Hydrogeochemical and pollution characterization of a shallow glauconitic sandstone aquifer in a peri-urban setting of Bobo-Dioulasso, southwestern Burkina Faso
“…In Niger, Morocco, and Madagascar, 1,057,000, 58,810, and 33,812 tons, respectively, were landfilled, while 12,145, and 1698 tons, were incinerated in Madagascar and in Benin, respectively. Unregulated waste dumping sites have been identified as the source of Pb, Hg, Ni, Cu, Cr, Cd, and Zn in the main source of groundwater abstraction in southwestern Burkina Faso, where informal settlements and peri-urban agriculture place the population at risk 32 . Waste disposal and its incineration have been identified in Kinshasa, Democratic Republic Congo, among the main sources of Cd, Pb, and Ni in ambient air 33 .…”
Countries globally trade with tons of waste materials every year, some of which are highly hazardous. This trade admits a network representation of the world-wide waste web, with countries as vertices and flows as directed weighted edges. Here we investigate the main properties of this network by tracking 108 categories of wastes interchanged in the period 2001–2019. Although, most of the hazardous waste was traded between developed nations, a disproportionate asymmetry existed in the flow from developed to developing countries. Using a dynamical model, we simulate how waste stress propagates through the network and affects the countries. We identify 28 countries with low Environmental Performance Index that are at high risk of waste congestion. Therefore, they are at threat of improper handling and disposal of hazardous waste. We find evidence of pollution by heavy metals, by volatile organic compounds and/or by persistent organic pollutants, which are used as chemical fingerprints, due to the improper handling of waste in several of these countries.
“…In Niger, Morocco, and Madagascar, 1,057,000, 58,810, and 33,812 tons, respectively, were landfilled, while 12,145, and 1698 tons, were incinerated in Madagascar and in Benin, respectively. Unregulated waste dumping sites have been identified as the source of Pb, Hg, Ni, Cu, Cr, Cd, and Zn in the main source of groundwater abstraction in southwestern Burkina Faso, where informal settlements and peri-urban agriculture place the population at risk 32 . Waste disposal and its incineration have been identified in Kinshasa, Democratic Republic Congo, among the main sources of Cd, Pb, and Ni in ambient air 33 .…”
Countries globally trade with tons of waste materials every year, some of which are highly hazardous. This trade admits a network representation of the world-wide waste web, with countries as vertices and flows as directed weighted edges. Here we investigate the main properties of this network by tracking 108 categories of wastes interchanged in the period 2001–2019. Although, most of the hazardous waste was traded between developed nations, a disproportionate asymmetry existed in the flow from developed to developing countries. Using a dynamical model, we simulate how waste stress propagates through the network and affects the countries. We identify 28 countries with low Environmental Performance Index that are at high risk of waste congestion. Therefore, they are at threat of improper handling and disposal of hazardous waste. We find evidence of pollution by heavy metals, by volatile organic compounds and/or by persistent organic pollutants, which are used as chemical fingerprints, due to the improper handling of waste in several of these countries.
“…For example, along with the Coastal Islands and Arid Regions, Na levels rich up to thousands of mg/l depending upon the well's location and depth. An increase in Na in Groundwater above ambient or natural levels may indicate pollution from the point or non-point sources or saltwater intrusion [88].…”
This review presents a detailed analysis of hydrogeological and hydrochemical conditions of the Niger Delta Basin. Hydrogeologically, the specific capacities recorded from different areas within this Basin vary from 6700 lit/hr/m to 13,500 lit/ hr/m. The water table is very close to the ground surface and varies from 0 to 4 meters. Unconfined groundwater aquifers occur in shallow unconfined aquifers, sands of the coastal beach ridges and river point bars, and sandy islands within the mangrove belt. There is a stable water table fluctuation which characterised the high precipitation zone. The shallow aquifers of Benin Formation are more porous than those in the Deltaic areas. In the southern areas, along the coastal zone, an artesian condition occurs. However, the aquifers are less transmissible with increased depth of the confined aquifer, owing to its more delicate texture. Therefore, more compact, and less permeable, or that there is not enough water in storage. More than half of groundwater sources in the Basin are acidic. Based on mean TDS concentration groundwater, fall in an excellent class for drinking. Groundwater classification based on conductivity showed all the reported findings indicate conductivity ranging from 250-750 μS/cm. Based on cation and anion chemistry, the Niger Delta Basin holds water of relatively acceptable drinking quality. However, the uncontrolled groundwater development, land-use changes, pollution from industrial, municipal, and agricultural effluents pose a threat to groundwater quality protection. Thus, a policy guideline is required to protect groundwater from pollution.
“…In comparison to more homogenous karst aquifer, higher degree of heterogeneity in karst hydraulical characteristics results in rapid changes of spring water quality (Fiorillo and Malik 2019). The mainly hydrochemical analyzes of karst groundwater used in the literature (as summarized in Table 1) including: adopting hydrogeochemical diagrams, e.g., Piper trilinear, Durov and Gibbs (Ghobadi et al 2018;Gao et al 2020;Davraz and Batur 2021;Hoaghia et al 2021); development of hydrochemical indices, e,g., chloro-alkaline and saturation index (Ndoye et al 2018;Hussien et al 2016;Hwang et al 2017Sako et al 2020; statistical methods, e.g., principle factor analysis, cross-correlation analysis, and principal component analysis (Ndoye et al 2018;Sako et al 2020;Vrouhakis et al 2021); and stable isotope analysis (Ghobadi et al 2018;Tang et al 2021). It can be noted that aside from hydrograph and chemograph analysis which usually requires only spring discharge and hydrochemical time-series data, other methods including detailed site-specific speleological investigation (Ford and Williams 2007), tracer tests (Goldscheider and Neukum 2010), hydrograph analysis (Fiorillo 2014) and model ensembles (Fandel et al 2020) are either expensive to implement, time-consuming or require more data input.…”
Karst groundwater resources in the Zagros Mountains are vital for supplying of different demands in the region which need to sustainable management and protection. Quantitative and qualitative characterization of karst aquifers in this region were understudied due to lack of site-specific logging-data and speleological investigations. In this study, a state-of-the-art of the statistical methods developed to characterize karst aquifer based on analyses of the spring recession hydrograph and spring water quality are presented. These methods including Manging’s method for classification of karst aquifers, relationships of precipitation and discharge data, groundwater quality index (GQI), hydrochemical diagrams (Piper, Durov and Gibbs), and Saturation index (SI), Chloro-Alkaline indices (CAI). 42 major karst springs mainly located in folded part of Zagros region (western Iran) are selected for application of the reviewed methods. Results indicated that the saturated zone exerts almost main control over the discharge of 76% of the studied springs. The base-flow contributes as between 80.0% to 100% of total water storage in the study aquifers. 78.5% of the studied aquifers have a high karstification degree. An insignificant lag-time is observed between the precipitation on the karst basin and spring discharge. The hydrochemical diagrams show that the waters are dominated by HCO3 and Ca and the majority of the waters are alkaline, with originate from silicate minerals weathering. Such repeatable methods adopted in this study can provide crucial information of the karst aquifers, especially those suffer scarcity of aquifer hydrodynamic data.
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