Hydrogenation of Carbon Dioxide to Methanol over Non−Cu‐based Heterogeneous Catalysts

Abstract

of Catalysis at Dalian Institute of Chemical Physics. His research interests include (1) CO 2 hydrogenation to chemicals and fuels, (2) methanol steam reforming to hydrogenation, and (3) liquid solar fuel synthesis.

Recent Progress in Direct DME Synthesis and Potential of Bifunctional Catalysts

“…Unfavorable factors in Cu‐based catalysts are the increased mobility of ZnO when water is formed, the limited stability due to sintering and agglomeration, and partly pyrophoric properties 64, 65. Amongst many others, 66 precious metal‐based catalysts are a general alternative to this 67 as they have high stability and often better resistance to sintering and poisoning.…”

Highly dispersed Cd cluster supported on TiO2 as an efficient catalyst for CO2 hydrogenation to methanol

“…Besides, Cu-based catalysts usually suffer from deactivation caused by sintering [17]. Thus, non-Cu catalysts have drawn increasing attentions in recent years [18]. For instance, MnO x /m-Co 3 O 4 [19], Co@SiO 2 [20], and MoS 2 [21] were reported to be able to selectively hydrogenate CO 2 to methanol.…”

Tuning product selectivity in CO2hydrogenation over metal-based catalysts

“…[2][3][4][5][6] In these transformations, CO 2 hydrogenation over metal-based catalysts is a critical route, but the intricate transformation network and multiple active sites strongly influence the product selectivity. [7][8][9][10][11] In recent years, various chemicals in CO 2 hydrogenation have been achieved, including CO, [12][13][14][15][16][17][18][19][20][21][22] methane, [23][24][25][26][27] methanol, [28][29][30][31][32][33][34][35][36][37] olefins, [38][39][40][41] gasolines, [42][43][44][45][46] aromatics, [47][48][49][50]…”