Hydrogen Storage in Pure and Boron-Substituted Nanoporous Carbons—Numerical and Experimental Perspective

Abstract

Nanoporous carbons remain the most promising candidates for effective hydrogen storage by physisorption in currently foreseen hydrogen-based scenarios of the world’s energy future. An optimal sorbent meeting the current technological requirement has not been developed yet. Here we first review the storage limitations of currently available nanoporous carbons, then we discuss possible ways to improve their storage performance. We focus on two fundamental parameters determining the storage (the surface accessible for adsorption and hydrogen adsorption energy). We define numerically the values nanoporous carbons have to show to satisfy mobile application requirements at pressures lower than 120 bar. Possible necessary modifications of the topology and chemical compositions of carbon nanostructures are proposed and discussed. We indicate that pore wall fragmentation (nano-size graphene scaffolds) is a partial solution only, and chemical modifications of the carbon pore walls are required. The positive effects (and their limits) of the carbon substitutions by B and Be atoms are described. The experimental ‘proof of concept’ of the proposed strategies is also presented. We show that boron substituted nanoporous carbons prepared by a simple arc-discharge technique show a hydrogen adsorption energy twice as high as their pure carbon analogs. These preliminary results justify the continuation of the joint experimental and numerical research effort in this field.

State-of-the-Art 2D and Carbon Nanomaterials in France

“…In addition, the exploration of hydrogen storage in nanoporous carbons holds promise for unlocking the potential of hydrogen-based energy systems. A review in this Special Issue explores the possibilities of nanoporous carbons for effective hydrogen storage by physisorption, highlights the current limitations, and proposes strategies to improve storage performance, including chemical modifications of carbon pore walls [9]. Preliminary results of boron-substituted nanoporous carbons have demonstrated promising improvements in hydrogen adsorption energy, encouraging further research in this field.…”