Hydrogen storage capacities of some new Hg(II) complexes containing 2-acetylethiophene

Novel dithiocarbamate–Hg(II) complexes containing mixed ligands: Synthesis, spectroscopic characterization, and H2 storage capacity

“…The results show that the BET surface area of complex (2) was 76.3 m 2 /g, while it was 41.1 m 2 /g for complex 3, and these results are in agreement with the results of particle sizes and with BET of our previous works. [25,26] This may be due to the increase in the surface area with decreasing size or due to the presence of SO 2 group in complex 2, causing high repulsion.…”

“…Among all hydrogen storage methods, the method of storage in the solid phase has been extensively used. [25][26][27][28][29] The most common chemicals used for this purpose are metal-organic compounds. [30,31] Our previous interests in the study of the coordination chemistry of heterocyclic ligands containing nitrogen, oxygen, and sulfur in their composition [26,[32][33][34] inspired us to choose the following ligands to receive more information about how N, O, and S compete between them in the coordination system around the metal studied.…”

Hydrogen Storage Capacity and Thermodynamic Calculations of Mercury(II) and Palladium(II) Syn‐2‐Pyridine Aldoxime Complexes

“…Currently there is an increasing interest in hydrogen storage as a new source of clean, eco-friend, and high density of energy. [47][48][49][50][51][52][53] The uses of hydrogen as an energy source is very interesting as it does not include side products that may pollutant the atmosphere or increase the global warming, which is the big world's problem these days. It has also a positive effect by impacts on current climate change.…”

“…Hydrogen can be stored as solid (stored in solids), liquid, or gaseous phase, but the best way includes storing into a solid materials as it is easy to dealing with, cheaper, and easier to transport. [57,58] As a part of our interest in studying the hydrogen storage capacity of metal complexes, [47][48][49][50][51][52][53] we reported here in a comparative study of hydrogen storage capacity of mercury(II) and palladium(II) aldoxime complexes.…”

Synthesis, characterization and multi-dimensional application approach for two distinctive tetra nuclear, first-time reported, Fe3+/Hg2+ and Fe3+/Cd2+ clusters from a new Fe3+ containing metalloligand

“…19,20 Cd 2+ and Hg 2+ complexes can exhibit different geometries from linear to octahedral or even distorted bipyramidal, hexagonal, and serious distortions from optimal polyhedral coordination are found to be natural phenomena due to adaptable coordination environment. [21][22][23][24] Additionally, the span of Cd 2+ and Hg 2+ coordination compounds are affected by other factors such as binding site, ligand flexibility, experimental conditions, and solvent molecules. 25,26 In spite of their structural beauty, the toxic nature of these aforementioned metals restrict their use in several sectors.…”