2018
DOI: 10.1021/acs.jced.8b00627
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Hydrogen Sorption Characteristics of Ordered Mesoporous Carbons: Experimental and Modeling View Point

Abstract: Ordered mesoporous carbons NCCR-41, NCCR-56, CMK-3, CMK-1, NCCR-11, and CMK-8 with varying pore size and pore dimensionality are prepared by adopting a nanocasting method employing sucrose as a carbon source and various ordered mesoporous silica templates. Systematic characterization of all the materials is done by various analytical and imaging techniques. Excess hydrogen sorption isotherms at 77 K and room temperature at high pressures are obtained using volumetric technique experiments. Correlation of the h… Show more

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Cited by 6 publications
(6 citation statements)
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“…A more advanced description of the flow through the spatial system of capillaries in the form of meandering channels is also found in Brinkhman [ 79 ]. The literature on the subject discusses other models of hydrodynamics of single and multiphase fluids flowing through porous media, taking into account the influence of fluid properties and the type of porous medium on the flow through granular beds [ 80 , 81 , 82 , 83 , 84 , 85 , 86 , 87 ]. A separate group of the practical use of the gas permeability methods is studies on the quality assessment of construction materials, particularly concretes [ 88 , 89 , 90 , 91 , 92 ].…”
Section: Resultsmentioning
confidence: 99%
“…A more advanced description of the flow through the spatial system of capillaries in the form of meandering channels is also found in Brinkhman [ 79 ]. The literature on the subject discusses other models of hydrodynamics of single and multiphase fluids flowing through porous media, taking into account the influence of fluid properties and the type of porous medium on the flow through granular beds [ 80 , 81 , 82 , 83 , 84 , 85 , 86 , 87 ]. A separate group of the practical use of the gas permeability methods is studies on the quality assessment of construction materials, particularly concretes [ 88 , 89 , 90 , 91 , 92 ].…”
Section: Resultsmentioning
confidence: 99%
“…The 1-D hexagonal and 3-D cubic OMCs were prepared using the nanocasting method, which employed ordered mesoporous silica as hard templates [43][44][45][46][47][48][49][50][51][52] and acidied sucrose as a carbon source. Likewise, all the MNCs were also synthesized using SBA-15 silica as a hard template 53,54 and the precursors used for synthesizing these N-doped carbons are ethylene diamine, pdiaminobenzene, aniline, pyrrole, and polyvinylpyrrolidone (PVP).…”
Section: Materials Synthesismentioning
confidence: 99%
“…Compared with mesoporous silicon materials, mesoporous carbon materials have several special excellent properties, such as high specific surface area and porosity, adjustable pore size, controllable pore wall composition and structure, simple synthesis, and a lack of physiological toxicity. At the same time, high thermal and hydrothermal stability and extremely large specific surface area and pore volume can be obtained by optimizing and controlling the synthesis conditions, thus making this type of material very promising for a wide range of applications, including in adsorbent carriers [20,36], catalyst supports [37,38,39], hydrogen storage materials [40,41,42], and electrode materials [43,44,45].…”
Section: Carbon-based Nanomaterialsmentioning
confidence: 99%