1995
DOI: 10.1016/0360-3199(94)00130-r
|View full text |Cite
|
Sign up to set email alerts
|

Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

2
70
0

Year Published

2006
2006
2016
2016

Publication Types

Select...
5
4

Relationship

0
9

Authors

Journals

citations
Cited by 113 publications
(72 citation statements)
references
References 22 publications
2
70
0
Order By: Relevance
“…A pressure correction formulae is also provided by Rase (1977) to extrapolate the experimental data normally carried out at atmospheric pressure to industrial data. Amadeo and Laborde (1995) made an analysis of five model equation, 2 representing redox mechanism and 3 representing Langmuir Hinshelwood model. They found the LH model which included the adsorption of the four components and surface reaction controlling the reaction provided best fit to their experimental results.Based on their experimental results, they provided a modified LH model for the low temperature shift reaction.…”
Section: Macro Kinetic Modelsmentioning
confidence: 99%
“…A pressure correction formulae is also provided by Rase (1977) to extrapolate the experimental data normally carried out at atmospheric pressure to industrial data. Amadeo and Laborde (1995) made an analysis of five model equation, 2 representing redox mechanism and 3 representing Langmuir Hinshelwood model. They found the LH model which included the adsorption of the four components and surface reaction controlling the reaction provided best fit to their experimental results.Based on their experimental results, they provided a modified LH model for the low temperature shift reaction.…”
Section: Macro Kinetic Modelsmentioning
confidence: 99%
“…Most of them show the negative effect of the presence of one or both reaction products. [26][27][28] In our case, the major difference was obtained for the CuO/Al 2 O 3 sample at 150°C, reaching a CO conversion of only 33% when the reaction products are present in the reactor feed, compared with 87% in their absence. At 150°C both Cu-based catalysts are shown to be strongly affected by the presence of CO 2 and H 2 .…”
Section: Effect Of Reaction Products In the Feed Compositionmentioning
confidence: 99%
“…This fact is also in agreement with the positive reaction order with respect to water obtained in power law rates. 23,[26][27][28]42 For the Au/TiO 2 sample the activity results in the temperature range 150-200°C are not influenced by the water vapor content. For higher temperatures the increase in the water vapor content above 35.39% (v/v) does not bring any change in the CO conversion, clearly opposed to what happens with the other catalysts.…”
Section: Effect Of the H 2 O Content In The Feedmentioning
confidence: 99%
“…The bulk of global H2 production still originates from the conversion of hydrocarbon fuels such as coal, crude oil, natural gas and biomass, and the co-production of CO2 necessitates a H2/CO2 separation process to deliver H2 of the desired purity to downstream processes [1,2]. Pressure swing adsorption (PSA) is a reliable, established technique for this separation, but is less than ideal from an efficiency and size perspective.…”
Section: Introductionmentioning
confidence: 99%