Hydrogen production from ammonia borane hydrolysis catalyzed by non-noble metal-based materials: a review

Wang, Chenyang; Zhao, Jianling; Du, Xiaosheng; Sun, Shuo; Yu, Xiaofei; Zhang, Xinghua; Lu, Zunming; Li, Lanlan; Yang, Xiaojing

doi:10.1007/s10853-020-05493-7

Cited by 38 publications

(23 citation statements)

References 160 publications

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“…It should be noted that the potential of active iron-containing components in the catalytic processes discussed in this study is still little studied. However, there have been some reported results dealing with the promoting action of iron on active nickel and cobalt-active components [ 8 , 10 , 57 , 58 , 59 , 60 ].…”

Section: Resultsmentioning

confidence: 99%

“…A comparison of the results for the activity of copper and cobalt ferrites in reaction media having different reducing powers (solutions of NH 3 BH 3 , NH 3 BH 3 +NaBH 4 and NaBH 4 ) confirmed the easier reduction of the copper-containing oxide. It has been suggested [ 10 ] that this happens because of the easier reduction of copper in the hydride medium to produce hydridic Cu-H species accelerating reduction of other metals in the oxide structure. The activating action of the compounds of copper, including its oxides, is well known and has been employed in the processes of hydrogenation of different organic substrates where ammonia borane is used as a mild reducer [ 61 , 62 , 63 ].…”

Section: Discussionmentioning

confidence: 99%

“…Ammonia borane (NH 3 BH 3 , AB) is an extensively studied hydride and dozens of review articles have already appeared discussing the results of these studies [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 ]. The high hydrogen content of this hydride (19.6 wt%) allows it to be applied in a variety of fields: as hydrogen storage systems to generate hydrogen for the needs of hydrogen economy [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 ], as a component of fuels [ 11 , 12 ], as a reducing agent in fine organic synthesis [ 13 ] and in the synthesis of metallic nanoparticles [ 14 , 15 ].…”

Section: Introductionmentioning

confidence: 99%

“…This process is traditionally carried out in an excess of water at room temperature in the presence of various catalysts [ 8 , 9 , 10 , 18 , 19 ]. Because of the high content of water, this process has a low value of gravimetric hydrogen density (GHD < 1 wt%), which is calculated using the ratio of the mass of released hydrogen to the total mass of all reactants and components of the hydrogen-generating system.…”

Section: Introductionmentioning

confidence: 99%

“…An analysis of the literature shows that copper is one of the most important components of the catalysts for AB hydrolysis [ 10 , 30 ]. In 2008, Kalidindi et al [ 26 ] showed the activity of the catalysts decreases in the order Cu 2 O > Cu@Cu 2 O > Cu.…”

Section: Introductionmentioning

confidence: 99%

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Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane

et al. 2021

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The paper presents a comparative study of the activity of magnetite (Fe3O4) and copper and cobalt ferrites with the structure of a cubic spinel synthesized by combustion of glycine-nitrate precursors in the reactions of ammonia borane (NH3BH3) hydrolysis and hydrothermolysis. It was shown that the use of copper ferrite in the studied reactions of NH3BH3 dehydrogenation has the advantages of a high catalytic activity and the absence of an induction period in the H2 generation curve due to the activating action of copper on the reduction of iron. Two methods have been proposed to improve catalytic activity of Fe3O4-based systems: (1) replacement of a portion of Fe2+ cations in the spinel by active cations including Cu2+ and (2) preparation of highly dispersed multiphase oxide systems, involving oxide of copper.

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Section: Resultsmentioning

confidence: 99%

Section: Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane

et al. 2021

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Transfer Hydrogenation of Azoarenes to Hydrazoarenes by Ammonia Borane Complex Catalyzed by Au Nanoparticles

Zantioti‐Chatzouda,

Malliotaki,

Stratakis

2023

Adv Synth Catal

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Minute amounts of supported Au nanoparticles on TiO2 (0.1 mol%) catalyze quantitatively at room temperature the transfer hydrogenation of azoarenes to hydrazoarenes by ammonia borane complex, in ethanol as solvent. At 1 mol% catalyst loading level and 2.5 molar equivalents of ammonia borane the process occurs instantaneously. The catalyst is recyclable and reusable. In the absence of reducing agent, hydrazoarenes undergo smooth Au/TiO2‐catalyzed aerobic oxidation back to azoarenes.

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Methanolysis of ammonia borane using binder‐free hierarchical Co@Ni metal‐organic framework nanocolumn arrays catalyst for hydrogen generation

Dharman

Prabu

Chiang

et al. 2022

Intl J of Energy Research

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Summary Ammonia borane (AB) is a potential material for chemical hydrogen storage because of its outstanding stability, high hydrogen density, and the development of highly effective hierarchical catalysts for AB hydrolysis. Herein, the hierarchical Co@Ni metal‐organic framework (MOF) nanocolumn arrays (NCAs) on nickel foam (NF) were fabricated through a simple hydrothermal reaction, and the prepared catalysts were characterized using different techniques. The hierarchical Co@Ni‐MOFNCA/NF acts as a catalyst for AB methanolysis for hydrogen production. The catalysts exhibited outstanding performance towards AB methanolysis with the TOF of TOF of 20.54 mol H2 mol catalyst−1 min−1. As a result, the activation energy of the Co@Ni‐MOF NCA catalyst is 39.72 kJ mol−1 which is compared with some commercial solid support materials such as Al2O3 and AC. Additionally, the effects of nanocatalyst loading and temperatures were studied for the Co@Ni‐MOF NCA catalyst. Further, a complete investigation proposes that the outstanding catalytic performance of the Co@Ni‐MOF NCA catalyst could be attributed to the synergy between Co and Ni‐MOF NCA.

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Hydrogen production from ammonia borane hydrolysis catalyzed by non-noble metal-based materials: a review

Cited by 38 publications

References 160 publications

Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane

Catalytic Behavior of Iron-Containing Cubic Spinel in the Hydrolysis and Hydrothermolysis of Ammonia Borane

Transfer Hydrogenation of Azoarenes to Hydrazoarenes by Ammonia Borane Complex Catalyzed by Au Nanoparticles

Methanolysis of ammonia borane using binder‐free hierarchical Co@Ni metal‐organic framework nanocolumn arrays catalyst for hydrogen generation

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