Methane hydrate is believed to contain a massive amount of potentially extractable hydrogen gas due to methane as the main component. A high-frequency argon jet plasma method has been proposed for decomposing hydrogen content. The excitation temperature of plasma can be directly observed from atomic emission lines. This information is more efficient to characterize the plasma behavior to optimize the decomposition process. In this study, the plasma excitation temperature was determined using spectroscopy and Boltzmann’s plot with a higher argon gas flow rate. An argon gas flow rate varied from 300, 400, 500, 1000, 1500, 2000, 2500, and 3000 mL/min. It flows inside a hollow tube in the counter electrode. A 27.12MHz high-frequency power source of plasma was applied to produce jet plasma at atmospheric pressure. The excitation temperature was observed in the range of 4310K to 5133K. The highest excitation temperature of 5133K was obtained at an argon gas flow rate of 500 mL/min.