Hydrogen permeability of a barium-aluminoborosilicate glass—A methodical approach

Ried, Peter; Gaber, Martin; Müller, Ralf; Deubener, Joachim

doi:10.1016/j.jnoncrysol.2014.04.006

Cited by 5 publications

(5 citation statements)

References 26 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…D and S were measured with the vacuum extraction device equipped with mass spectrometry (VHE) as described in detail in [8], [11]. For this purpose, glass powders (80-105 mg) were exposed to pressurised hydrogen at different temperatures for different exposure times to ensure that the hydrogen loading was fully saturated.…”

Section: Hydrogen Gas Permeation Through Glassmentioning

confidence: 99%

“…with t = isothermal degassing time, r = radius of the glass sphere, Q(t) = amount of hydrogen released at t and Q 0 = total amount of dissolved hydrogen. Herein, a uniform radius of glass spheres was assumed, which was taken from d 50 of the measured particle size distribution [11]. As the ratio Q(t)/Q ∞ is dimensionless, D was fitted in terms of I H2 , the VHE hydrogen ion current (in A) (Fig.…”

Section: Hydrogen Gas Permeation Through Glassmentioning

confidence: 99%

See 1 more Smart Citation

Hydrogen Permeability of Tectosilicate Glasses for Tank Barrier Liners

et al. 2023

View full text Add to dashboard Cite

The permeation of hydrogen gas was studied in meta-aluminous (tectosilicate) glass powders of Li2O×Al2O3×SiO2 (LAS), Na2O×Al2O3×SiO2 (NAS) and MgO×Al2O3×SiO2 (MAS) systems by pressure loading and vacuum extraction in the temperatures range 210–310 °C. With this method, both the solubility S and the diffusivity D were determined, while the permeability was given by the product SD. For all glasses, S was found to decrease with temperature, while D increased. Since the activation energy of diffusion of H2 molecules exceeded that of dissolution, permeation increased slightly with temperature. When extrapolated to standard conditions (25 °C), the permeability of tectosilicate glasses was found to be only 10-22–10-24 mol H2 (m s Pa)-1, which is 8–10 magnitudes lower than most polymers. Thin glass liners of these compositions are expected to be the most effective barrier for tanks of pressurised hydrogen.

show abstract

Section: Hydrogen Gas Permeation Through Glassmentioning

confidence: 99%

Section: Hydrogen Gas Permeation Through Glassmentioning

confidence: 99%

Hydrogen Permeability of Tectosilicate Glasses for Tank Barrier Liners

et al. 2023

View full text Add to dashboard Cite

show abstract

“…For commercial aluminoborosilicate glasses, we can assume that all aluminum and boron are fourfold coordinated and stabilized by modifier ions. Then, NBO/T is given as: Barton (Barton and Morain, 1970), Tsugawa (Tsugawa et al, 1976), Leiby (Leiby and Chen, 1960), Altemose (Altemose, 1961(Altemose, , 1962Shelby, 1996), Norton (Norton, 1953), Barrer (Barrer, 1934), Johnson (Johnson and Burt, 1922), Lee et al (Lee et al, 1962), Lee (Lee, 1963), Massaryk (Masaryk, 1968), Ried (Ried et al, 2014), Shelby (Shelby, 1974b(Shelby, , 1977a(Shelby, , 1996, Laska , and Walters (Walters, 1970 (Shelby, 1973(Shelby, , 1974a(Shelby, , 1996Shelby and Eagan, 1976;Ried et al, 2014).…”

Section: Compositional Dependencementioning

confidence: 99%

“…Experimental studies, which are limited to fused silica and commercial borosilicate glasses (Johnson and Burt, 1922;Barrer, 1934;Altemose, 1961;Lee et al, 1962;Morimoto et al, 1992;Shelby, 1996;Kurita et al, 2002), alkali-alkaline earth silicate glasses (Barton and Morain, 1970) and aluminoborosilicate glasses (Ried et al, 2014) show that isothermal permeability can vary up to three orders of magnitude. The underlying principles in the correlations between glass composition, accessible free volume and hydrogen permeation are still unclear.…”

Section: Introductionmentioning

confidence: 99%

“…FIGURE 1 | Permeation constant P 0 (A) and activation energy E P (B) of hydrogen and deuterium permeation vs. the molar percentage of network formers G. Data:Barton (Barton and Morain, 1970), Tsugawa(Tsugawa et al, 1976),Leiby (Leiby and Chen, 1960), Altemose(Altemose, 1961(Altemose, , 1962Shelby, 1996), Norton(Norton, 1953),Barrer (Barrer, 1934), Johnson(Johnson and Burt, 1922),Lee et al (Lee et al, 1962), Lee(Lee, 1963), Massaryk(Masaryk, 1968), Ried(Ried et al, 2014), Shelby(Shelby, 1974b(Shelby, , 1977a(Shelby, , 1996, Laska, and Walters(Walters, 1970). Dashed line represents Tsugawa's compositional dependence [Equation (4)].…”

mentioning

confidence: 99%

See 1 more Smart Citation

Hydrogen Permeation Through Glass

et al. 2020

View full text Add to dashboard Cite

Physical storage of gaseous hydrogen under high-pressure in glassy micro-containers such as spheres and capillaries is a promising concept for enhancing safety and the volumetric capacity of mobile hydrogen storage systems. As very low permeation through the container wall is required for storage of compressed hydrogen, development of glasses of minimal hydrogen permeability is needed. For this purpose, one has to understand better the dependence of hydrogen permeability on glass structure. The paper points out that minimizing the accessible free volume is a sound strategy to minimize hydrogen permeability. Based on previously measured and comprehensive literature data, it is shown that permeation is independently controlled by ionic porosity and network modifier content. Thus, ionic porosity in modified and fully polymerized networks can be decreased equally to the lowest hydrogen permeability among the glasses under study. Applying this concept, a drop of up to 30,000 with respect to the permeation of hydrogen molecules through silica glass is attainable.

show abstract