Hydrogen generation from hydrazine on N4 moieties graphene embedded by vanadium metal, DFT calculation

Activation of NO2 by Modifying the Porphyrin Unit with Oxygen in a MnN4 Graphene Layer

“…[9,10] Because pure Graphene is inert towards chemical reactions and has some drawbacks to its usage as a capture material, [11][12][13] various strategies can be applied to enhance its activity such as doping foreign atoms, creating vacancies, embedding foreign atoms into the different kind of vacancies and functionalizing by substitution of different p and d-block elements. [14][15][16][17][18][19][20] So far, a large number of publications aimed to investigate NO 2 interaction mechanism with the functionalized two-dimensional (2D) catalytic surfaces because this is the first step of aim no matter what the application is. [21][22][23][24][25][26][27][28][29][30] Liang and colleague have investigated the NO 2 adsorption characteristics on Mnembedded carbon materials including MnN 4 graphene layer.…”

“…For this kind of capture and catalytic applications, Graphene received spectacular interest since it was fabricated [9,10] . Because pure Graphene is inert towards chemical reactions and has some drawbacks to its usage as a capture material, [11–13] various strategies can be applied to enhance its activity such as doping foreign atoms, creating vacancies, embedding foreign atoms into the different kind of vacancies and functionalizing by substitution of different p and d‐block elements [14–20] …”