Three molecular Re hydrides of the form (Rbpy)Re(CO)3H with 2,2′-bipyridine (bpy) ligands
containing silatrane
functional groups for surface attachment on metal oxide surfaces were
synthesized. IR spectroscopy and cyclic voltammetry (CV) demonstrated
that the complexes containing the silatrane functional groups have
electronic properties similar to those of a control compound, which
did not contain functional groups for attachment. Additionally, in
a similar fashion to the control compound, the silatrane containing
Re hydrides are electrocatalysts for the reduction of CO2 to CO in solution. The silatrane containing complexes were immobilized
on a thin layer of TiO2 on Si, and the resulting composites
were characterized using X-ray photoelectron and IR spectroscopy as
well as cyclic voltammetry in the dark and under illumination. Control
experiments indicated that the hydride complexes are not stable on
the surface and degrade to species which contain a bpy ligand, three
CO ligands, and an unknown ligand in the sixth site. Similarly, when
one of the silatrane containing Re hydride complexes was immobilized
on Si nanoparticles with a thin layer of SiO2 or silica
nanoparticles, the hydride ligand was lost. Density functional theory
calculations were used to corroborate the observed behavior of hydride
species on a surface. Overall, this work demonstrates the difficulties
associated with attaching well-defined molecular hydride complexes
to metal oxide surfaces.