Abstract:[a] R. V. Kapustin [a] and I. V. Vorotyntsev [a] Keywords: FTIR spectroscopy; low temperatures; hydrogen bond; haloforms; silicon; germanium tetrachloride; trichlorosilane.The FTIR study allowed to reveal that a hydrogen bond can arise in low -temperature films at 20 K between chloroform, bromoform and tetrachlorides of silicon and germanium, as well as a dihydrogen bond between chloroform and trichlorosilane. The general scheme of molecular interaction was simulated by ab initio calculation in terms of … Show more
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