“…[5][6][7] Moreover, the carbohydrate-bearing polymers, especially synthetic polymers with pendant sugar moieties (known as glycopolymers), have found applications mostly in biomedicine and as biomaterials. [8][9][10][11] Therefore, there have been many studies on the preparation of glycopolymers with a large diversity of architectures, [12][13][14][15] using different approaches like conventional and controlled radical polymerization, living anionic polymerization, cyanoxyl-mediated polymerization, ring opening polymerization and post-polymerization modification. A classic example is the obtaining of methacrylic glycomonomers with hydroxyl protected groups, such as 3-O-methacryloyl-1,2:3,4-di-O-isopropylidene-d-galactopyranose, [16][17][18] but the proposed methods are cumbersome and involve toxic solvents.…”