Hydroformylation of simple olefins catalyzed by metals and clusters supported on unfunctionalized inorganic carriers

One-Pot Liquid-Phase Catalytic Conversion of Ethanol to 1-Butanol over Aluminium Oxide—The Effect of the Active Metal on the Selectivity

“…1-Butanol can be synthesized by several routes such as the oxo-process [5][6][7][8][9][10], the acetaldehyde method or by fermentation.…”

Rhodium(I) and rhodium(III)–heteropolyacids supported on MCM-41 for the catalytic hydroformylation of styrene derivatives

“…After the hydroformylation reaction of styrene, two new bands were observed to developed, 2040 and 1661 cm À1 . The two peaks are tentatively attributed to Z-ORhCO(PhCHCH 2 ) and Z-O-Rh(Ph(CH 3 )COCH 3 ) (Z = support), respectively [22].…”

Preparation of Rh-TPPTS complex intercalated layered double hydroxide and influences of host and guest compositions on its catalytic performances in hydroformylation reaction

“…Table 6 lists the catalytic results for the three catalyst systems studied. The effect of co-intercalated inorganic anions (NO 3 , Cl and SO 4 2 respectively) on catalytic performances was investigated.…”

“…7 million tones per year) [2] . Over the past few decades, development and application of immobilized hydroformylation catalysts have been attracting widespread interest [3,4] , since such catalysts can combine the high activity and selectivity of homogeneous catalysts with the long lifetime and ease of separation of heterogeneous catalysts [5] . A large number of papers and patents concerning alkene hydroformylation reactions catalyzed by rhodium or other noble metal complexes supported on silica or other oxide supports have been published [6,7] , with some showing high performance.…”

“…There were some reports on intercalation of transition metal complexes in LDHs which have shown good catalytic activity. Examples include reusable OsO 4 2 on ion-exchangers for asymmetric dihydroxylation of olefins [15] , LDHs-host catalysts for stereoselective epoxidation [16] and LDHs-WO 4 2 for mild oxidative bromination [17] .…”