X-ray flow visualization in a half-zone molten silicon bridge was carried out under microgravity at a variety of oxygen partial pressures in an ambient atmosphere. The flow velocity of thermocapillary convection was found to decrease with increased oxygen partial pressure. Thermocapillary flow stabilized when the oxygen partial pressure at the inlet p O 2 was increased to 10 Ϫ4 MPa. The dependence of the flow velocity and flow mode on p O 2 can be explained in terms of the decrease in the temperature coefficient of surface tension due to the increase in oxygen partial pressure. Single crystals of semiconductor silicon have been widely used for advanced computer and mobile communication devices. To improve the quality of silicon single crystals, the transfer of heat and mass at the solid-liquid interface during crystal growth must be better understood. In industrial crystal growth processes, such as the Czochralski ͑CZ͒ or the float-zone ͑FZ͒ methods, there are three types of convection: buoyancy, forced, and thermocapillary convection. Of these, the thermocapillary effect at the free surface is dominant, especially under microgravity. 1 Thermocapillary convection also plays a significant role in forming dopant striations in the crystal growth process. Eyer et al. 1 carried out silicon crystal growth in a float-zone system under microgravity and showed that timedependent thermocapillary convection caused the dopant striations. Cröll et al. 2 found that the critical Marangoni number, M a c2 , for the transition from steady to time-dependent flow was 150 Ϯ 50. The thermocapillary flow in a molten silicon bridge has previously been investigated by measuring temperature fluctuations and visualizing flow. 3-7 Nakamura et al. 7 observed thermocapillary flow by using X-ray radiography with tracer particles in a molten silicon bridge, and they showed that the frequency of the tracer motion in the bridge formation process differed from that of the complete bridge. There have also been many reports on numerical simulations of thermocapillary convection in a half-zone bridge in low Prandtl number fluids such as molten silicon. [8][9][10][11][12][13][14][15] These simulations indicated that transition processes occur first, from an axisymmetric flow to a three-dimensional steady flow and then from a threedimensional steady flow to a three-dimensional oscillatory flow. Most studies, however, have not taken into consideration the influence of oxygen partial pressure in the ambient atmosphere on thermocapillary convection of molten silicon.The Marangoni number, which indicates the potential for thermocapillary convection, depends on the temperature coefficient of surface tension, the temperature difference between the upper and lower interfaces, and the height of the molten zone. In many investigations of thermocapillary convection in molten silicon, the temperature coefficient of surface tension has been assumed to be constant. However, in the case of molten silicon, oxygen partial pressure in an ambient atmosphere is though t...