Hydrodynamic voltammetry at the liquid–liquid interface: Application to the transfer of ionised drug molecules

Mechanism of Ion Transfer in Supported Liquid Membrane Systems: Electrochemical Control over Membrane Distribution

“…Peaks 1 and 3 of Figure 4 b were used for an accurate current–scan rate gradient analysis using eq 4 (NPOE data in Table 3 ). The unusual behavior of partially charged species at the interface between two immiscible liquids, which has been described previously for a simple liquid–liquid system, 49 gives rise to a complex ionization and distribution equilibrium and hindered accurate quantitative analysis of rhodamine B in terms of the models for SLM transport, as further discussed in the Supporting Information (S-5).…”

Voltammetric study of the partitioning of macrolide antibiotics at the water/nitrobenzene interface. Relationship to the pharmacokinetic profiling of macrolides

“…It was found that diffusion coefficients calculated using Randles-Ševčik equation depended on the actual pH of the aqueous phase. For azithromycin diffusion coefficients in aqueous phase ranged from 1. interface as already described by Velický et al [20]. No kinetically slow steps were detected in the cyclic voltammograms.…”

Facilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases

“…The imposition of a convective flow to increase the mass-transport has also been reported [43][44][45][46][47][48][49][50][51][52][53][54][55][56][57]. Recently, Dryfe and co-workers [29] presented a novel method, which employed an…”