Abstract. The study provided the major ion chemistry, chemical weathering
rates and temporary and net CO2 sinks in the Bei Jiang, which was
characterized as a hyperactive region with high chemical weathering rates,
carbonate and silicate mixing lithology, and abundant sulfuric acid chemical
weathering agent of acid deposition and acid mining drainage (AMD) origins.
The total chemical weathering rate of 85.46 t km−2 a−1 was comparable to that of other rivers in the
hyperactive zones between the latitudes 0 and 30∘. A carbonate weathering rate
of 61.15 t km−2 a−1 contributed to about
70 % of the total. The lithology, runoff, and geomorphology had a significant
influence on the chemical weathering rate. The proportion of carbonate
outcrops had a significant positive correlation with the chemical weathering
rate. Due to the interaction between dilution and compensation effect, a
significant positive linear relationship was detected between runoff and
total carbonate and silicate weathering rates. The geomorphology factors
such as catchment area, average slope, and hypsometric integral value (HI)
had nonlinear correlation with chemical weathering rate and showed
significant scale effect, which revealed the complexity in chemical
weathering processes. Dissolved inorganic carbon (DIC) apportionment showed that CCW (carbonate
weathering by CO2) was the dominant origin of DIC (35 %–87 %). SCW
(carbonate weathering by H2SO4) (3 %–15 %) and CSW (silicate
weathering by CO2) (7 %–59 %) were non-negligible processes. The
temporary CO2 sink was 823.41×103 mol km−2 a−1.
Compared with the temporary sink, the net sink of CO2 for the
Bei Jiang was approximately 23.18×103 mol km−2 a−1 of CO2 and was about 2.82 % of the “temporary”
CO2 sink. Human activities (sulfur acid deposition and AMD)
dramatically decreased the CO2 net sink, even making chemical
weathering a CO2 source to the atmosphere.