Hydroboration-oxidation of ricinoleic acid derivatives

Муслухов, Р. Р.; Shayakhmetova, A. Kh.; Yakovleva, M. P.; Shitikova, O. V.; Ishmuratov, G. Yu.; Толстиков, Г. А.

doi:10.1134/s1070428008080046

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“…NHC–Ir complexes (NHC=N‐heterocyclic carbene) have proven to be excellent catalysts in numerous processes, particularly in dehydrogenations and transfer hydrogenations . ,,, NHCs can be relatively easily functionalized to provide the desired reactivity. Their versatility has recently been highlighted by Peris in a recent review article, in which the author refers to NHCs as “smart ligands”.…”

Section: Introductionmentioning

confidence: 99%

Nonclassical Mechanism in the Cyclodehydration of Diols Catalyzed by a Bifunctional Iridium Complex

Miera

Bermejo‐López

Martínez‐Castro

et al. 2019

Chemistry A European J

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1,4‐ and 1,5‐diols undergo cyclodehydration upon treatment with cationic N‐heterocyclic carbene (NHC)–IrIII complexes to give tetrahydrofurans and tetrahydropyrans, respectively. The mechanism was investigated, and a metal‐hydride‐driven pathway was proposed for all substrates, except for very electron‐rich ones. This contrasts with the well‐established classical pathways that involve nucleophilic substitution.

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