Abstract:The hydroboration of substituted cyclopropanes has been investigated using the B3LYP density functional method employing 6-31G** basis set. Borane moiety approaching the cyclopropane ring has been reported. It is shown that the reaction proceeds via a three-centered, “loose” and “tight,” transition states when boron added to the cyclopropane across a bond to a substituents. Single point calculations at higher levels of theory were also performed at the geometries optimized at the B3LYP level, but only slight c… Show more
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