Hydrido Phosphine Complexes of Rhodium(I)

Hydrogen/Deuterium Exchange Reactions of Olefins with Deuterium Oxide Mediated by the Carbonylchlorohydrido‐ tris(triphenylphosphine)ruthenium(II) Complex

“…RuHCl(CO)A C H T U N G T R E N N U N G (PPh 3 ) 3, [41] RuHClA C H T U N G T R E N N U N G (PPh 3 ) 3, [42] and OsHCl(CO)A C H T U N G T R E N N U N G (PPh 3 ) 3 [43] were synthesized according to reported procedures. 1,4-Dioxane was purged with nitrogen for 10 min before use.…”

Ruthenium-catalyzed β-alkylation of secondary alcohols with primary alcohols

“…Other solvents were purged with nitrogen for 10 min before use. CpRuCl(dppe) [28], CpRuH(dppe) [29], Cp ⁄ RuCl(COD) [30], Cp ⁄ RuCl(PPh 3 ) 2 [31], RuHCl(CO)(PPh 3 ) 3 [32], RuH 2 (CO)(PPh 3 ) 3 [32], {[(p-cymene) RuCl(NH 2 CH 2 CH 2 O)] 2 H}Cl [33], (p-cymene)RuCl(NH 2 CH 2 CH 2 NTs) Cl [34], (p-cymene)RuCl 2 (PPh 3 ) [35], Ru(OAc) 2 (PPh 3 ) 2 [36], RuCl 2 (PPh 3 ) 2 (2,2 0 -bipyridine) [37], RuCl 2 (NH 2 CH 2 CH 2 NH 2 )(PPh 3 ) 2 [38], RuCl 2 (dppf)(2-PyCH 2 NH 2 ) [39], RuCl 2 (dppb)(2-NH 2 CH 2 Py) [26], RuCl 2 (2-H 2 NCH 2 Py)(PPh 3 ) 2 [26], RuCl 2 (PPh 3 ) 3 [40], RuCl 2 (DMSO) 4 [41], CpRuCl(PPh 3 ) 2 [42], and RuCl 2 (PPh 3 )(2,2 0 :6 0 ,2 00 -terpyridine) [43] were prepared following the procedures described in the literature. All other reagents were used as purchased from Aldrich Chemical Co., Acros Organics, International Laboratory (USA), or Kodak.…”

Synthesis, characterization, and properties of binuclear ruthenium complexes with dendritic side chains on their bridges

“…Solvents were pre-dried, distilled and degassed prior to use, except those for spectroscopic measurements, which were of spectroscopic grade. The starting materials RuHCl (CO)(PPh 3 ) 3 [36], 5-(bromomethyl)-1,3-bis{[4-(tert-butyl)benzyl] oxy}benzene [37,38], 1,3-bis[ (3,5-bis{[4-(tert-butyl)benzyl]oxy} benzyl)oxy]-5-(bromomethyl)benzene [37,38], and 2,5-bis(2-(trimethylsilyl)ethynyl)benzene-1,4-diol [39] were prepared by the procedures described in literature methods. 1 Elemental analyses (C, H, N) were performed by Vario ElIII Chnso.…”