“…Hydrogenation properties are very sensitive to these modifications, and in some cases, substantial changes of the hydrogenation behavior can be obtained after milling. For example, the formation of nanocrystalline or amorphous structure produced by milling results in dramatic changes in hydrogenation properties, especially by eliminating the need for activation and improving hydrogenation/dehydrogenation kinetics [33,45,46].…”
“…Hydrogenation properties are very sensitive to these modifications, and in some cases, substantial changes of the hydrogenation behavior can be obtained after milling. For example, the formation of nanocrystalline or amorphous structure produced by milling results in dramatic changes in hydrogenation properties, especially by eliminating the need for activation and improving hydrogenation/dehydrogenation kinetics [33,45,46].…”
“…However, as previously stated, TiN, BN, ZrN, and Fe 3 N have been produced by reactive ball milling the respective metals in a nitrogen or ammonia milling atmospher [79][80][81][82][83][84][85][86][87][88][89][90].…”
Section: Results Of Synthesizing Dyn Via a Direct Nitridation Synthesmentioning
confidence: 99%
“…The only reports found for nitriding metals are those discussing the synthesis of TiN, BN, ZrN, and Fe 3 N in a nitrogen or ammonia milling atmosphere [79][80][81][82][83][85][86][87][88][89][90]. The work presented in this report is the first that has been documented demonstrating the direct nitridation of dysprosium and cerium metal via a mechanical ball milling route [92].…”
Section: Novel Reactive Milling Synthesis Route To Cenmentioning
“…For sake of simplicity, isothermal and mechanical processing conditions will be hereafter referred to respectively as static and dynamic conditions. Additional details on experimental procedures can be found elsewhere [25,29].…”
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