“…Some years later, Jardani et al (2007) proposed a more precise empirical relationship that has been proven to be very useful as it decreases the number of variables to be estimated and provides good estimates of effective excess charge for different types of porous media. This relationship has been used in many studies involving electrokinetic phenomena, such as dam leakage (e.g., Bolève et al, 2009;Ikard et al, 2014), surface-groundwater interaction (e.g., Linde et al, 2011), seismoelectric studies (e.g., Mahardika et al, 2012;Monachesi et al, 2015;Revil et al, 2015), hydraulically active fracture identification (e.g., Roubinet et al, 2016), and permeability field characterization (e.g., Jardani & Revil, 2009;Soueid Ahmed et al, 2014). However, equation (26) has been obtained regardless of pore water composition and other hydraulic parameters of porous media.…”