1977
DOI: 10.1016/0040-4020(77)80374-8
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Hybridization in propellanes

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1979
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Cited by 23 publications
(7 citation statements)
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References 40 publications
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“…Published estimations of its orbital hybridization 50,51 fall into a wide and ambiguous range between sp 0.5 -sp 0.5 and sp 5 -sp 5 . A further and more straightforward guide could be gained from the present high-quality calculations of J(C,C) between bridgehead carbons in propellane treated on the grounds of the multipath coupling mechanism.…”
Section: Propellanementioning
confidence: 98%
“…Published estimations of its orbital hybridization 50,51 fall into a wide and ambiguous range between sp 0.5 -sp 0.5 and sp 5 -sp 5 . A further and more straightforward guide could be gained from the present high-quality calculations of J(C,C) between bridgehead carbons in propellane treated on the grounds of the multipath coupling mechanism.…”
Section: Propellanementioning
confidence: 98%
“…169.1 (s), 154.2 (s), 104.5 (t), 76.6 (d), 43.1 (d), 39.3 (t), 38.1 (d), 36.7 (t), 33.8 (t), 32.0 (d), 31.6 (t), 27.7 (d), 20.9 (q) 155.7 (s), 103.4 (t), 83.6 (d), 55.3 (q), 42.9 (d), 39.5 (t), 38.6 (d), 36.9 (t), 33.5 (t), 31.8 (d), 31.4 (t), 28.0 (d) 4.96 (br s, 1 11), 4.63 49.7 (d), 40.7 (d), 40.0 (t), 35.0 (t+d), -2.5-1.1 (nr) 34.6 (t), 31.7 (t), 30.2 (t), 27.6 (d), 25.3 (d) 8c 79.2 (s), 50.1 (q), 42.7 (d), 35.4 (d), 35.1 (t), 3.07 (s, 3 ), 2.3-1.0 (in, 15 H) 34.8 (t), 32.7 (t), 31.7 (t), 31.1 ((), 30.1 (d), 29.0 (d), 26.3 178 (M+, 100), 135 ( 27), 109 (59), 105 (30). 91 (70), 79 (78), 77 (65)…”
Section: Resultsunclassified
“…144.5 (s), 134.7 (s), 129.8 (d), 129.5 (d), 63.3 (s) , 61.9 (s), 50.1 (d), 42.1 (t), 39.6 (d), 35.0 (t) , 32.4 (t), 30.9 (t), 28.4 (d), 27.7 (t), 24.5 (d), 21.3 (q) 135.9 (d), 133.9 (s), 128.7 (d), 127.8 (d), 54.6 (s) , 43.8 (d), 36.9 (t), 36.2 (d), 36.0 (d), 34.9 (t) , 34.6 (t), 32.5 (t), 30.7 (t), 28.8 (d), 25.9 (d)…”
Section: Resultsunclassified
“…In addition to Wiberg's results, other theories have also been suggested. 18,[24][25][26][27] Ginsburg [28][29][30] and Wiberg 19,31,32 have reviewed the syntheses and the theoretical studies of propellanes extensively, Wiberg concentrating on the small-ring propellanes and Ginsburg on the medium-sized rings. In his book entitled 'Propellanes', Ginsburg even describes the syntheses and structures of natural products possessing the propellane structure.…”
Section: Propellanes and Their Synthesismentioning
confidence: 99%