“…[17][18][19][20] Profit from the direct band structure, excellent optoelectronic properties, and controlled fabrication routes, ZnO (the bandgap ∼ 3.37 eV, large excitation binding energy ∼ 60 eV at room temperature), attracts tremendous potential as a candidate for preparing high-performance heterostructural optoelectronic devices, by combing other p-type semiconductor materials at the absence of steady, reliable and repeatable p-type ZnO. 13,[21][22][23][24][25] Currently, rapid advances in ZnO/Si-based heterojunction have made it possible to modulate the optoelectronic performance, and great efforts have been conducted to fabricating ZnO/Si optoelectronic devices, like light source, photodiode, and solar cell, etc. Because of the limitation of Si materials and technology, it is remain a severe challenge to developing high-performance Si-based optoelectronic devices, especially for high-efficiency LEDs and photodetectors.…”