Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks

Abstract

Domestic and foreign literature on methods for obtaining graphene and its derivatives [graphene oxide (GO) and reduced GO] as representatives of the family of 2D layered materials is analyzed. Particular attention is paid to GO. Great potential of post-synthetic modification as well as unique properties of the material and its derivatives make them promising for a variety of applications including biomedicine, ecology, optoelectronics, etc. Chemical and physical methods for the reduction of GO to obtain graphene-like materials similar in structure and properties to pure graphene obtained by direct mechanical cleavage are considered. Functionalization strategies of graphene materials are discussed. The preparation of hydro- and organogels as well as Pickering emulsions from graphene derivatives as precursors of porous monoliths are considered. The formation of aerogels based on graphene materials and methane adsorption on these porous structures are discussed. Basic information about hybrid materials containing graphene derivatives and metal-organic frameworks is given and their adsorption characteristics with respect to methane are evaluated. Covalent and noncovalent interactions in graphene – porphyrin hybrids are considered from the standpoint of formation of porphyrin architectures on the surface of graphene materials. Examples of the use of porphyrin – graphene composite materials in photo- and electrocatalysis, fuel cells and gas separation membranes are given. The bibliography includes 243 references.

Graphene Oxide Protected Copper Benzene-1,3,5-Tricarboxylate for Clean Energy Gas Adsorption

“…The combination of the unique features of HKUST-1 and graphene or graphene derivatives was found to improve the performance of the associated system in several applications. Recent review articles on the subject confirm the interest in such composites [ 38 , 39 , 40 ]. The enhancement of the electrochemical catalytic activity of HKUST-1@graphene derivative composite materials enabled the development of electrochemical sensors for H 2 O 2 [ 41 ], NH 3 [ 42 ], paracetamol and dopamine [ 43 ].…”

Evolution of graphene oxide (GO)-based nanohybrid materials with diverse compositions: an overview

“…In a series of works tetraphenyl and tetrakis-hydroxyphenyl derivatives of PP (TPP and THPP) along with their Co and Zn-complexes have been used to design metal–organic frameworks with improved performance compared to GO towards photocatalytic, fuel cell and gas separation applications. 220 In a series of works tetraphenyl and tetrakis-hydroxyphenyl derivative of PP (TPP, THPP) along with their Co and Zn-complexes has been used to design metal–organic framework with GO having improved performance than GO itself towards photocatalysis, electrocatalysis, fuel cell, methane sorbent and gas separation applications. 220 …”

Functionalized heterocycle-appended porphyrins: catalysis matters

“…For example, a series of hybrid materials was constructed with tetrapyrrole active sites and inert inorganic supports for the resolution of complicated problems. [15][16][17][18][19][20][21][22] It should be noted that solving applied problems using the material chemistry approach always requires extensive preliminary investigations. This inevitably leads to the need to elaborate novel synthetic pathways and the extension of series of known classes of macroheterocyclic compounds with optimized electronic, chemical and physicochemical properties.…”

“…In the framework of our ongoing projects, our investigations are focused on tetrapyrrolic compounds, namely porphyrins and phthalocyanines, and their synthetic modications and search for new types of applications. 17,[23][24][25][26][27][28][29][30][31][32][33] Recently, we developed synthetic strategies towards imidazole-and pyrazine-annulated porphyrins starting from tetrapyrrole dioxo-or diamino-derivatives and aromatic aldehydes. 28,[34][35][36][37][38] The sterically hindered tetrapyrrole was used as a synthetic platform for the development of bifunctionalized linear and angular annulated polyaromatic compounds, water soluble derivatives for biomimetic applications and macrocycles with terminal anchoring groups.…”