Uniform single-crystalline Fe 3 O 4 nanowires have been prepared at 150°C via a simple hydrothermal route assisted by polyethylene glycol (PEG600). Morphology and molecular structure of the Fe 3 O 4 nanowires have been studied by means of scanning and transmission electron microscopy, X-ray diffraction, and infrared spectroscopy. Fe 3 O 4 nanowires have been studied as an additive promoting thermal decomposition of ammonium perchlorate; their catalytic performance has been investigated by thermal gravimetric analysis. Temperature of ammonium perchlorate decomposition decreases by about 50°C upon addition of Fe 3 O 4 nanowires.1 The text was submitted by the authors in English. One-dimensional (1D) nanostructures such as nanotubes [1], nanofibers [2], nanowires [3], nanorods [4], etc have been paid increasing attention over the recent decades, owning to the unique properties and promising applications in various nanoscale devices [5]. Many papers have focused on preparation of nanoscale materials based on metals and metal oxides , etc.) showing novel electronic, optical, catalytic, and magnetic properties [6-9]. Among the 1D-structured materials, magnetite (Fe 3 O 4 ) nanowires have attracted great interest in the magnetic materials field [10] in view of the potential applications as magnetic recording media [11], magnetic supports [12], catalyst [13], ferrofluids [14], etc. Ammonium perchlorate (AP) is a common oxidizing agent used as component of various propellants [15], and features of its thermal decomposition are highly relevant to combustion behavior of the solid propellants. Extensive studies of AP thermal decomposition have revealed its efficient catalysis with many transition metal oxides [16]. In particular, certain 1D nanostructured metal oxides (e.g., ZnO [17], CuO [18], Fe 2 O 3 [19], etc.) can promote AP decomposition.In this paper, we report on catalytic activity of magnetite (Fe 3 O 4 ) nanowires towards decomposition of AP as studied by TGA and DTG techniques.Magnetite nanowires were prepared via a facile hydrothermal synthesis in the presence of polyethylene glycol PEG600. The product X-ray diffraction pattern (Fig. 1a) contained the six characteristic reflections at