2013
DOI: 10.1016/j.apcatb.2013.03.048
|View full text |Cite
|
Sign up to set email alerts
|

Hybrid Cu–ZnO–ZrO2/H-ZSM5 system for the direct synthesis of DME by CO2 hydrogenation

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1
1

Citation Types

5
81
0
1

Year Published

2013
2013
2023
2023

Publication Types

Select...
6
2
1

Relationship

0
9

Authors

Journals

citations
Cited by 141 publications
(87 citation statements)
references
References 60 publications
5
81
0
1
Order By: Relevance
“…S7 of Supplementary Material. In line with this result, Bonura et al [23] have recently reported a superior performance in the direct CO 2 conversion to DME for a Cu-ZnO-ZrO 2 /HZSM-5 hybrid catalyst prepared by physical mixing of pre-pelletized components with respect to that prepared by grinding of the powdered single components.…”
Section: Direct Dme Synthesis On Cza/zeolite Hybrid Catalystssupporting
confidence: 55%
“…S7 of Supplementary Material. In line with this result, Bonura et al [23] have recently reported a superior performance in the direct CO 2 conversion to DME for a Cu-ZnO-ZrO 2 /HZSM-5 hybrid catalyst prepared by physical mixing of pre-pelletized components with respect to that prepared by grinding of the powdered single components.…”
Section: Direct Dme Synthesis On Cza/zeolite Hybrid Catalystssupporting
confidence: 55%
“…As shown in Figure 7d, it has been discovered that the core where the reaction happens is mainly constituted by CuO and ZnO phases, decorated by ZrO2 crystal, where the diffraction plane (002) and (200) corresponds to CuO phase, (101) relative to ZnO phase, and (111) of ZrO2 tetragonal phase is well distinguishable [48]. Combining with the results mentioned above, we determined that the adsorption properties of H2 and CO2 could be greatly influenced by the catalyst composition, leading to the different reaction activities.…”
Section: Discussion On the Synergetic Effect Of Czz Catalystmentioning
confidence: 99%
“…Other examples of using zeolites in CO 2 conversion to bulk chemicals include CO 2 hydrogenation to form methanol in a zeolite (zeolite A) membrane reactor [ 133 ] and, by further reacting with in situ formed methanol, to produce dimethyl ether over a Cu-ZnO-ZrO 2 /H-ZSM5 catalyst. [ 134 ] In addition to industrial processes for bulk chemicals, modifi ed zeolites, acting as base catalysts, have also shown ability to promote cycloaddition of CO 2 to epoxides. Potassium exchanged zeolite X (or KX) loaded with Cs + ions have shown a high activity for adding CO 2 onto ethylene oxide to form ethylene carbonate (reaction equation shown in Figure 5 ), [ 135 ] which is a useful chemical as a plasticizer as well as an electrolyte in lithium batteries.…”
Section: Zeolites For Co 2 Conversionmentioning
confidence: 99%