Hybrid composites of lanthanide metal–organic frameworks with epoxy silanes for highly sensitive thermometry

Abstract

Post-synthetic modification of metal-organic frameworks (MOF) and fabrication of hybrid composites are currently hot topics in the development of new functional materials. In this study, a facile and direct approach...

Long aliphatic chain derivatives of trigonal lanthanide complexes

“…Thus, Ln complexes that can be modified by various groups to either tune their properties or give them new features (for instance allow for deposition on various surfaces or solubility in various media) offer interesting perspectives. Postmodification is well-known for both transition metal-based metal organic frameworks (MOFs) [22][23][24] and Ln-containing MOFs, 25,26 where it is used to tune or change physical properties as well as introducing new functions. However, post-modification of single Ln complexes where the first coordination sphere around the Ln ion remains unchanged upon modification are to the best of our knowledge rare.…”