We introduce the notion of Mixed Symmetry Quantum Phase Transition (MSQPT) as singularities in the transformation of the lowest-energy state properties of a system of identical particles inside each permutation symmetry sector µ, when some Hamiltonian control parameters λ are varied. We use a three-level Lipkin-Meshkov-Glick (LMG) model, with U (3) dynamical symmetry, to exemplify our construction. After reviewing the construction of U (3) unirreps using Young tableaux and Gelfand basis, we firstly study the case of a finite number N of three-level atoms, showing that some precursors (fidelity-susceptibility, level population, etc.) of MSQPTs appear in all permutation symmetry sectors. Using coherent (quasi-classical) states of U (3) as variational states, we compute the lowest-energy density for each sector µ in the thermodynamic N → ∞ limit. Extending the control parameter space by µ, the phase diagram exhibits four distinct quantum phases in the λ-µ plane that coexist at a quadruple point. The ground state of the whole system belongs to the fully symmetric sector µ = 1 and shows a four-fold degeneracy, due to the spontaneous breakdown of the parity symmetry of the Hamiltonian. The restoration of this discrete symmetry leads to the formation of four-component Schrödinger cat states.