A robust mathematical treatment of the Ozawa/Flynn/Wall isoconversion method is conducted to determine the value and uncertainty of the activation energy and pre‐exponential factor for the degradation of polypropylene (PP) in thermogravimetric analysis (TGA) experiments at constant heating rates. In the present work are employed mathematical models and uncertainty propagation techniques, based on the Guide to the Expression of Uncertainty in Measurement (GUM) to estimate the Arrhenius activation energy and preexponential factor due the uncertainty of the integration constant b, both in a linear and a third‐degree reciprocal polynomial model with respect to x. The error arising from Doyle's linear approximation in the improper integral of temperature in the Arrhenius equation is examined, and an alternative method is proposed to correct this error, reducing it to 0.032% in the working interval of ̶ 200 ≤ x ≤ ̶ 15, where x = ̶ E/RT. Given the increased sensitivity of modern TGA equipment, these improvements are considered essential for obtaining reliable results that align with experimental precision limits compared to previous works. Thus, this allows for the development of an enhanced quality assurance framework by providing a more robust uncertainty estimation and better understanding of the method, leading to more reliable results. Moreover, this approach can be applied to other similar polymer systems.This article is protected by copyright. All rights reserved