How well do standard laboratory methods represent the field water retention curve of volcanic ash soils (Andosols)?

Abstract

<p>Accurate determination of the water retention curve (WRC) of a soil is essential for the understanding and modelling of the subsurface hydrological, ecological, and biogeochemical processes. Volcanic ash soils with andic properties (Andosols) are recognized as important providers of ecological and hydrological services in mountainous regions worldwide due to their outstanding water holding capacity. Previous comparative analyses of in situ (field) and standard laboratory (hydrostatic equilibrium based) methods for the determination of the WRC of Andosols showed contrasting results. Based on an extensive analysis of laboratory, experimental, and field measured WRCs of Andosols in combination with data extracted from the published literature we show that standard laboratory methods using small soil sample volumes (≤300 cm<sup>3</sup>) mimic the WRC of these soils only partially. The results obtained by the latter resemble only a small portion of the wet range of the Andosols’ WRC (from saturation up to -5 kPa, or pF 1.7), but overestimate substantially their water content for higher matric potentials. The disagreement limits our capacity to infer correctly subsurface hydrological behavior, as illustrated through the analysis of long-term soil moisture and matric potential data from an experimental site in the tropical Andes. These findings imply that results reported in past research should be used with caution and that future research should focus on determining laboratory methods that allow obtaining a correct characterization of the WRC of Andosols.</p>