2005
DOI: 10.1016/j.cplett.2004.12.060
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How transparent are the imidazolium ionic liquids? A case study with 1-methyl-3-butylimidazolium hexafluorophosphate, [bmim][PF6]

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Cited by 227 publications
(217 citation statements)
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“…Recently, various spectroscopic measures (NMR, IR, Raman, etc.) were utilized to characterize the properties of RTILs [7][8][9]. Pulse radiolysis and time-resolved fluorescence [10][11][12][13][14][15][16] have also been applied to study the reaction processes occurring in RTILs.…”
Section: Introductionmentioning
confidence: 99%
“…Recently, various spectroscopic measures (NMR, IR, Raman, etc.) were utilized to characterize the properties of RTILs [7][8][9]. Pulse radiolysis and time-resolved fluorescence [10][11][12][13][14][15][16] have also been applied to study the reaction processes occurring in RTILs.…”
Section: Introductionmentioning
confidence: 99%
“…This originates from the internal high strain during ion insertion into and extraction from the particles [17]. However, in the SEM images In the XPS survey spectra of 0 vol% added EMImBF 4 , 1375.0 (C=C) at 285 eV and 270.0 (CF) at 285.5 eV, corresponding to C1s respectively, can be observed.…”
Section: Structural Properties Of Electrodes Surfacementioning
confidence: 99%
“…Recently, ILs have attracted much interest as ion conductive materials owing to their unusual properties, such as a wide voltage range, non-volatility, and non-flammability [15][16][17][18][19]. However, pure ILs have a viscosity higher than that of non-aqueous solvent, limiting their ionic diffusion.…”
Section: Introductionmentioning
confidence: 99%
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“…On the simple optical absorption curve, very high absorption appears between 90 and 95 mol%. In a previous study on [C 4 mim][PF 6 ] (Paul et al, 2005), the optical absorption in the UV-vis spectra was explained well. The electronic absorption around 4.4 eV in [C 4 mim][PF 6 ] provides information on the polarity of the RTIL and the dynamics of the diffusion.…”
Section: H/d Effects At 1 Mol% Water Mixturementioning
confidence: 99%