2022
DOI: 10.2139/ssrn.4167744
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How to Increase the Potential of Aqueous Zn-Mno2 Batteries: The Effect of Ph Gradient Electrolyte

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“…By increasing the H + concentration in the electrolyte, the dissolution reaction of MnO 2 during discharging can be enhanced (equation (6) and (7)). In the meantime, a higher voltage window up to ~2 V could be achieved [11] . However, it should be noted that parasitic reactions become severe at the Zn anode site in acidic medium, such as corrosion of Zn metal resulted in production of H 2 gas.…”
Section: Working Mechanismmentioning
confidence: 99%
“…By increasing the H + concentration in the electrolyte, the dissolution reaction of MnO 2 during discharging can be enhanced (equation (6) and (7)). In the meantime, a higher voltage window up to ~2 V could be achieved [11] . However, it should be noted that parasitic reactions become severe at the Zn anode site in acidic medium, such as corrosion of Zn metal resulted in production of H 2 gas.…”
Section: Working Mechanismmentioning
confidence: 99%