A hot, T e ~ 2-to 3-keV surface plasma was observed in the interaction of a 0.7-ps petawatt laser beam with solid copper-foil targets at intensities >10 20 W/cm 2 . Copper K-shell spectra were measured in the range of 8 to 9 keV using a single-photon-counting x-ray CCD camera. In addition to K α and K β inner-shell lines, the emission contained the Cu He α and Ly α lines, allowing the temperature to be inferred. These lines have not been observed previously with ultrafast laser pulses. For intensities less than 3 × 10 18 W/cm 2 , only the K α and K β inner-shell emissions are detected. Measurements of the absolute K α yield as a function of the laser intensity are in agreement with a model that includes refluxing and confinement of the suprathermal electrons in the target volume.2