Host–Guest-Interaction Enhanced Nitric Oxide Photo-Generation within a Pillar[5]arene Cavity for Antibacterial Gas Therapy
Haojie Wang,
Yuan Wang,
Wenhua Xu
et al.
Abstract:Supramolecular
macrocycles with intrinsic cavities have
been widely
explored as containers to fabricate versatile functional materials via specific host–guest recognitions. However, relatively
few studies have focused on the modulation of guest reactivity within
a macrocyclic cavity. Here, we demonstrate the confinement effect
of pillar[5]arene with an electron-rich and precise cavity that can
dramatically enhance guest photoactivity and nitric oxide (NO) generation
upon visible light irradiation. Mechanism s… Show more
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.