Homogeneous hydroformylation of long chain alkenes catalyzed by water soluble phosphine rhodium complex in CH<sub>3</sub>OH and efficient catalyst cycling

Li, Yanli; Zhao, Jiangui; Zhao, Yuan-jiang; Liu, Huimin; Fu, Haiyan; Zheng, Xueli; Li, Ruixiang; Chen, Hua

doi:10.1039/c8ra08787c

Cited by 13 publications

(5 citation statements)

References 31 publications

(29 reference statements)

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“…The system was reused four times and a gradual small decrease in activity was observed (99 to 80 %), while the aldehyde selectivity remained constant. Zheng [119] applied the same Rh/tppts catalytic system but with methanol as polar solvent. Using hex‐1‐ene as substrate, 98 % conversion was obtained, with 91 % acetal selectivity using 80 °C and 20 bar CO/H 2.…”

Section: Reusable Hydroformylation Catalystsmentioning

confidence: 99%

Reusable Catalysts for Hydroformylation‐Based Reactions

2021

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Catalytic hydroformylation is an important reaction, widely studied by academics and applied in the chemical industry, and it is a paradigmatic example of a chemical reaction that is aligned with most of the Green Chemistry principles. In the last years, the global requirement for more sustainable chemical processes has boosted the development of more active, selective, and reusable hydroformylation catalysts. In this review, we highlight the most recent advances regarding the creation and expansion of reusable catalysts for hydroformylation and sequential processes that use hydroformylation as central reaction. The most relevant strategies for immobilization of hydroformylation catalysts are discussed, along with a critical analysis of their application in synthesis, based on catalytic activity, selectivity, and reusability.

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Section: Reusable Hydroformylation Catalystsmentioning

confidence: 99%

Reusable Catalysts for Hydroformylation‐Based Reactions

2021

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“…Phosphine ligands can be coordinated to various transition metals (Pt, Pd, Rh, Ru etc.) for various applications such as hydroformylation, hydrogenation, Mizoroki-Heck and Suzuki cross-coupling reactions [9][10][11][12][13]. Our interests in phosphine ligands includes application of platinum complexes in catalytic as well as biological studies.…”

Section: Commentmentioning

confidence: 99%

The crystal structure of bis{3-(diphenylphosphaneyl)propanoato-κ² O,P}platinum(II) dihydrate, C₃₀H₂₈O₆P₂Pt

Moyo

Matsinha

Banothile

2020

Zeitschrift Für Kristallographie - New Crystal Structures

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Section: Introductionmentioning

confidence: 99%

“…In the early days, the reaction was mainly based on homogeneous Rh/Co complexes and phosphine-modified Rh/Co system catalysts. − Although these catalysts have been used commercially, research on the development of new catalysts for olefin hydroformylation has not stopped as a result of the harsh operating conditions (high temperature and high pressure). − Liu et al explored the methanol-diluted hydroformylation of long-chain olefins catalyzed by the Rh/TPPTS complex (TPPTS = sodium salt of sulfonated triphenylphosphine), and the system allowed for a wide range of olefin hydroformylation to be carried out under milder operating conditions (60–100 °C and 2 MPa). Hood et al developed a bisphosphine coordination Co(II) catalyst ([HCo(CO) n (P 2 )] + ) that still ensured high activity and selectivity under mild operating conditions.…”

Section: Introductionmentioning

confidence: 99%

Outlook of Cobalt-Based Catalysts for Heterogeneous Hydroformylation of Olefins: From Nanostructures to Single Atoms

Gao,

Liu,

Wang

et al. 2023

Energy Fuels

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Hydroformylation of olefins, as a study of olefinic downstream derivative production, is of great relevance in chemical production. Heterogeneous hydroformylation is beneficial for catalyst separation and recycling compared to homogeneous systems. Cobalt is a cheap metal with excellent catalytic activity in hydroformylation as well as the precious metal rhodium. Therefore, the research on cobalt-based catalysts for heterogeneous hydroformylation has great value and significance. The nano or atomic structures of cobalt-based catalysts have significant impact on the catalytic behaviors of the hydroformylation process. There is rarely the design principles report on how to achieve significant improvement in hydroformylation performance by regulating the structure of the cobalt-based catalyst. Herein, we review the recent research progress on heterogeneous hydroformylation by cobalt-based catalysts with different metal sizes (from nanostructures to single atoms). On the basis of the difference in the catalytic mechanism between homogeneous and heterogeneous hydroformylation, we summarize and propose the regulation principles to enhance the activity and stability of cobalt-based catalysts in hydroformylation, where single-atom engineering is expected to achieve unity of high activity and stability of cobalt-based catalysts for hydroformylation applications. At the end of this review, we present an outlook on the opportunities and challenges in developing cobalt-based catalysts for heterogeneous hydroformylation.

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Homogeneous hydroformylation of long chain alkenes catalyzed by water soluble phosphine rhodium complex in CH₃OH and efficient catalyst cycling

Abstract: Hydroformylation of long-chain alkenes proceeded homogeneously in methanol efficiently. The catalyst could be separated heterogeneously when methanol was removed and recycled for four times without obvious loss in catalytic performance and rhodium.

Cited by 13 publications

References 31 publications

Reusable Catalysts for Hydroformylation‐Based Reactions

Reusable Catalysts for Hydroformylation‐Based Reactions

The crystal structure of bis{3-(diphenylphosphaneyl)propanoato-κ² O,P}platinum(II) dihydrate, C₃₀H₂₈O₆P₂Pt

Outlook of Cobalt-Based Catalysts for Heterogeneous Hydroformylation of Olefins: From Nanostructures to Single Atoms

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Homogeneous hydroformylation of long chain alkenes catalyzed by water soluble phosphine rhodium complex in CH3OH and efficient catalyst cycling

Abstract: Hydroformylation of long-chain alkenes proceeded homogeneously in methanol efficiently. The catalyst could be separated heterogeneously when methanol was removed and recycled for four times without obvious loss in catalytic performance and rhodium.

Cited by 13 publications

References 31 publications

Reusable Catalysts for Hydroformylation‐Based Reactions

Reusable Catalysts for Hydroformylation‐Based Reactions

The crystal structure of bis{3-(diphenylphosphaneyl)propanoato-κ2 O,P}platinum(II) dihydrate, C30H28O6P2Pt

Outlook of Cobalt-Based Catalysts for Heterogeneous Hydroformylation of Olefins: From Nanostructures to Single Atoms

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Homogeneous hydroformylation of long chain alkenes catalyzed by water soluble phosphine rhodium complex in CH₃OH and efficient catalyst cycling

The crystal structure of bis{3-(diphenylphosphaneyl)propanoato-κ² O,P}platinum(II) dihydrate, C₃₀H₂₈O₆P₂Pt