Homogeneous catalytic aminocarbonylation of 1-iodo-1-dodecene. The facile synthesis of odd-number carboxamides via palladium-catalysed aminocarbonylation

Synthetic utility of tribenzyltin hydride and its derivatives as easily accessible, removable, and decomposable organotin reagents

“…The isolated products 8 were identified by 1 H and 13 C NMR analysis. The NMR data well agree with the reported data (8a [31], 8b [32], 8c [33] …”

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

“…A related mechanism involving CO insertion and Pd IV -alkynyl species has been proposed in aminocarbonylations of vinyl iodides, which is accompanied by the unexpected ynamide formation (Scheme 213). 290 However, in both reactions described above, the proposed Pd IV -alkynyl species remain highly speculative.…”

“…A related mechanism involving CO insertion and Pd IV −alkynyl species has been proposed in aminocarbonylations of vinyl iodides, which is accompanied by the unexpected ynamide formation (Scheme ) …”

Microwave-Assisted Carbonylation and Cyclocarbonylation of Aryl Iodides under Ligand Free Heterogeneous Catalysis

“…Palladium-catalyzed carbonylation of aryl halides in the presence of nucleophiles is an important atom-economic reaction that can be applied to the synthesis of a wide range of arylcarbonyl compounds such as ketones, carboxylic acids, esters, or amides that can be easily obtained either in solution , or in the solid phase . Most of the carbonylation procedures reported in the literature are based on the use of homogeneous Pd catalysts in the presence of phosphine ligands . However, an excess of phosphine is often required to avoid catalyst deactivation, and its separation from the reaction products and regeneration is usually difficult, limiting the applicability of carbonylation procedures …”