“…Nevertheless, the use of chirality inducers is reported in the construction of some octahedral complexes, metal–organic polymeric architectures such as coordination polymers, metal–organic frameworks (MOFs), and covalent organic frameworks from achiral building blocks. − Helical motifs with unique handedness are often realized in such examples, which are sustained by supramolecular interactions, including hydrogen bonds and π–π interactions, as well as the structural robustness of the frameworks. Such studies are continuously populating a library of enantiopure molecules, including camphoric acid, mandelic acid, cinchona alkaloids, ionic liquids, proline, 1-phenylethylamine, propane-1,2-diol, and camphorsulfonic acid, which may be considered as potential chiral inducers …”