Homochiral lanthanide metal–organic frameworks based on amino acid-functionalized terpyridyl ligand: synthesis, structure determination, and optical properties

Dong, Yingling; Sun, Hongzhi; Teng, Bao-Shan; Ma, Yuan-Jun; Wang, Xing; Wu, Ben‐Lai

doi:10.1016/j.ica.2020.119931

Cited by 3 publications

(1 citation statement)

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“…A similar effect was observed with a range of amino acids complexing to zinc(II) using several different crystallization methods (mechanochemical mixing, slurry and crystallization from solution) (Shemchuk et al, 2020b). Homochiral lanthanide MOFs have been synthesized using amino acid derivatives and were shown to have useful fluorescence properties (Dong et al, 2020).…”

Section: Introductionmentioning

confidence: 54%

A homochiral coordination polymer of cobalt(II) and L-serine

Majoumo-Mbe

Nfor

et al. 2021

Acta Crystallogr C

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A one-dimensional chiral cobalt(II) coordination polymer, namely, catena-poly[[[(S)-2-amino-3-hydroxypropanoato-κ2 N,O 1]cobalt(II)]-μ-(S)-2-amino-3-hydroxypropanoato-κ4 O 1,O 3:N,O 1′], [Co(C3H6NO3)2] n or Δ-[Co(L-Ser-κ2 N,O)2] n (L-Ser = L-serine) (1), has been synthesized and characterized using elemental and thermal analyses, IR spectroscopy and single-crystal and powder X-ray diffraction techniques. The asymmetric unit of 1 consists of two serine anions which are coordinated to a Co2+ ion to give three chelate rings. These extend the structure into a helical chain with pendant chelate rings which participate in interchain hydrogen bonding. The ability of 1 to undergo transmetallation was evaluated. Among a range of divalent metal ions, only copper(II) partially replaced cobalt(II).

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Section: Introductionmentioning

confidence: 54%