The development of inexpensive non-precious oxygen reduction catalysts has become one of the most important efforts in polymer electrolyte membrane fuel cells. In this report, we synthesized a non-precious electrocatalyst from a single precursor, iron (III) diethyelene triaminepentaacetate, using a heat-treatment effect to prepare an active catalyst. A series of catalysts were prepared at different temperatures leading to different degrees of graphitization, heteroatom content and activity. In 0.1M KOH electrolyte solution, the oxygen reduction reaction (ORR) onset potential of the HNCS71 catalyst was as high as 0.97V, and half-wave potentials were only 20mV lower than for Pt/C. X-ray absorption measurements of Fe Kedge showed the structure of Fe-N4 centers, formed in HNCS71, which were responsible for the ORR activity. An alkaline exchange membrane fuel cell made with HNCS71 as cathode was tested in H2-O2 single cell and showed a maximum power density of ~68 mW cm -2 . The 100-hour fuel cell durability test of HNCS71 cathode showed decays in current density of about 14% at 0.4 V. Therefore, the HNCS catalyst appears to be a promising new class of non-precious catalyst for fuel cell applications.