“…One of the classes of liquid crystalline stable radicals is based on the 6-oxoverdazyl radical, [28][29][30][31][32][33][34][35] which includes a series of bent-core 1,5-bis(aryloiloxyphenyl)-6-oxoverdazyls 1[m,n] (Fig. 1).…”
A mesogenic building block based on a 6-oxoverdazyl diradical possessing a robust triplet ground state (ΔES–T = 1.06(2) kcal mol−1) has been developed.
“…One of the classes of liquid crystalline stable radicals is based on the 6-oxoverdazyl radical, [28][29][30][31][32][33][34][35] which includes a series of bent-core 1,5-bis(aryloiloxyphenyl)-6-oxoverdazyls 1[m,n] (Fig. 1).…”
A mesogenic building block based on a 6-oxoverdazyl diradical possessing a robust triplet ground state (ΔES–T = 1.06(2) kcal mol−1) has been developed.
A novel approach to the preparation of stable Pd-substituted verdazyls was developed through the direct oxidative addition of iodoverdazyls to Pd(PPh3)4.
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