2022
DOI: 10.1016/j.cej.2021.131363
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HMX surface modification with polymers via sc-CO2 antisolvent process: A way to safe and easy-to-handle energetic materials

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Cited by 38 publications
(11 citation statements)
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“…Surface modification methods can be physical or chemical, and there are a variety of treatments available. Over the last few decades, these modification methods have been established with an emphasis on the surface incorporation of extra functionalities responsible for the growing increase of surface free energy (wettability) and tailored applications [25][26][27]. Such modifications should only affect the top surface area (tens of nm), which is essential for functional strength and at the same time to maintain integrity of the material.…”
Section: Introductionmentioning
confidence: 99%
“…Surface modification methods can be physical or chemical, and there are a variety of treatments available. Over the last few decades, these modification methods have been established with an emphasis on the surface incorporation of extra functionalities responsible for the growing increase of surface free energy (wettability) and tailored applications [25][26][27]. Such modifications should only affect the top surface area (tens of nm), which is essential for functional strength and at the same time to maintain integrity of the material.…”
Section: Introductionmentioning
confidence: 99%
“…This property decreases the absorption tendency of the CO 2 with HSLD temperature. In addition, with rise in temperature, viscosity of HSLD decreases due to weakening of cohesive force of HSLD 44 . This property of the HSLD is also responsible for decrease in CO 2 absorption 45 .…”
Section: Resultsmentioning
confidence: 98%
“…In addition, with rise in temperature, viscosity of HSLD decreases due to weakening of cohesive force of HSLD. 44 This property of the HSLD is also responsible for decrease in CO 2 absorption. 45 After the temperature of the HSLD reached 50 C, the amount of carbon dioxide in the HSLD remained unchanged, which indicates that the regeneration process is Actual CO 46 The boundary layer formation at higher CO 2 concentration, causes a shock wave of absorption which continues to rise after that.…”
Section: Effect Of Operating Time On Co 2 Absorptionmentioning
confidence: 99%
“…Lin et al [24] used a new high melting point paraffin wax (HPW) and PDA to coat HMX to obtain litchi-like microcapsules, which can significantly reduce the impact sensitivity and friction sensitivity and improve the thermal stability. Kosareva et al [25] used supercritical CO 2 as an anti-solvent to obtain polymer-coated HMX particles. The results show that the polymers at less than 3 wt% content can precipitate on the surface of HMX crystal as globular islands, which can significantly reduce the impact sensitivity.…”
Section: Introductionmentioning
confidence: 99%